Mechanical Properties and Biodegradability of Polyvinyl Alcohol and Potato Starch-Based Biocomposites with Lemon Peel Powder Filler
DOI:
https://doi.org/10.56862/irajtma.v4i3.335Keywords:
Polyvinyl Alcohol (PVA), Potato Starch, Lemon Peel, Mechanical Properties, BiodegradabilityAbstract
This study aims to examine the mechanical properties, surface morphology, and biodegradability of polyvinyl alcohol-potato starch biocomposites with lemon peel powder as a filler. The biocomposites were produced by solution casting with 1%, 2%, and 3% fillers of lemon peel powder. Mechanical properties were tested to determine tensile strength in accordance with ASTM D882. The addition of lemon peel powder increased tensile strength as the percentage content increased. The highest tensile strength was 4.82 MPa in polyvinyl alcohol-potato starch biocomposites containing 3% lemon peel powder. This indicates that lemon peel powder effectively improves bonding with the matrix and produces stronger interfacial bonds. However, the flexibility of the biocomposites decreased with increasing lemon peel powder content, as indicated by a decrease in elongation. Furthermore, the biodegradation of the biocomposites showed that the biocomposite with the highest lemon peel powder content (3%) exhibited the fastest degradation rate, reaching 65.22% after 15 days of testing. These results indicate that the presence of lemon peel powder improves the mechanical properties of the biocomposite without reducing its biodegradability. These findings indicate that biocomposites made from polyvinyl alcohol and potato starch with lemon peel powder are a promising sustainable plastic alternative, combining strength, flexibility, and degradability.
References
Abral, Hairul, Angga Hartono, Fadli Hafizulhaq, Dian Handayani, Eni Sugiarti, and Obert Pradipta. 2019. “Characterization of PVA/Cassava Starch Biocomposites Fabricated with and without Sonication Using Bacterial Cellulose Fiber Loadings.” Carbohydrate Polymers 206: 593–601. https://doi.org/10.1016/j.carbpol.2018.11.054.
Akhrib, Sofiane, Souad Djellali, Nacereddine Haddaoui, Davud Karimian, and Mauro Carraro. 2024. “Biocomposites and Poly(Lactic Acid) in Active Packaging: A Review of Current Research and Future Directions.” Polymers 17 (1): 3. https://doi.org/10.3390/polym17010003.
Al Rasyid, Mahmudin, Achmad Jusuf Zulfikar, and Iswandi Iswandi. 2022. “Analisis Kekuatan Tarik Komposit Laminat Jute Berdasarkan Pola Kerusakan Kolom Silinder Metode Split Tensile Test.” IRA Jurnal Teknik Mesin Dan Aplikasinya (IRAJTMA) 1 (2): 27–34. https://doi.org/10.56862/irajtma.v1i2.15.
Ali, Maimunah Asem Shehadeh Saleh, Dzun Noraini Jimat, Wan Mohd Fazli Wan Nawawi, and Sarina Sulaiman. 2022. “Antibacterial, Mechanical and Thermal Properties of PVA/Starch Composite Film Reinforced with Cellulose Nanofiber of Sugarcane Bagasse.” Arabian Journal for Science and Engineering 47 (5): 5747–54. https://doi.org/10.1007/s13369-021-05336-w.
Asrofi, Mochamad, Hilmy Dzaki Arisandi, Revvan Rifada Pradiza, et al. 2024. “Mechanical Properties of Biocomposite Films Based Polyvinyl Alcohol/Potato Starch Filled by Coffee Ground Waste.” International Journal of Agriculture and Biosciences 13 (3): 525–30. https://doi.org/10.47278/journal.ijab/2024.156.
Asrofi, Mochamad, Nur Achmad Asyari, Revvan Rifada Pradiza, et al. 2025. “Enhancing Mechanical and Thermal Properties of PVA-Abaca Fiber Biocomposites via Ultrasonic Vibration Bath Treatment.” Results in Engineering 25: 103935. https://doi.org/10.1016/j.rineng.2025.103935.
Asrofi, Mochamad, Dedi Dwilaksana, Hairul Abral, And Rahmat Fajrul. 2019. “Tensile, Thermal and Moisture Absorption Properties of Polyvinyl Alcohol (PVA) / Bengkuang (Pachyrhizus Erosus) Starch Blend Films.” Material Science Research India 16 (1): 70–75. https://doi.org/10.13005/msri/160110.
Asyraf, M R M, R A Ilyas, S M Sapuan, et al. 2022. “Advanced Composite in Aerospace Applications: Opportunities, Challenges, and Future Perspective.” In Advanced Composites in Aerospace Engineering Applications, edited by Norkhairunnisa Mazlan, S M Sapuan, and R A Ilyas. Springer International Publishing. https://doi.org/10.1007/978-3-030-88192-4_24.
Bharat, Nithesh, and Pulak Datta. 2024. “Evolution and Sustainability of Green Waste Valorization for the Development of Starch-Based Films: A Narrative Review.” Biomass Conversion and Biorefinery, ahead of print, December 7. https://doi.org/10.1007/s13399-024-06359-7.
Bourakadi, Khadija El, Nawal Merghoub, Meriem Fardioui, et al. 2019. “Chitosan/Polyvinyl Alcohol/Thiabendazoluim-Montmorillonite Bio-Nanocomposite Films: Mechanical, Morphological and Antimicrobial Properties.” Composites Part B: Engineering 172: 103–10. https://doi.org/10.1016/j.compositesb.2019.05.042.
Cao, Chunyan, Minkun Cai, Lingyu Zhao, and Gang Li. 2024. “Improving Water Stability of Soil Aggregates with Polyvinyl Alcohol as a Polymeric Binder.” Polymers 16 (13): 1758. https://doi.org/10.3390/polym16131758.
Delavari, Mohammad Mohsen, and Ion Stiharu. 2022. “Preparation and Characterization of Eco-Friendly Transparent Antibacterial Starch/Polyvinyl Alcohol Materials for Use as Wound-Dressing.” Micromachines 13 (6). https://doi.org/10.3390/mi13060960.
Fakraoui, Oumaima, Leonard Ionut Atanase, Slim Salhi, Isabelle Royaud, Mourad Arous, and Zoubir Ayadi. 2024. “Investigation of Lemon Peel Extract as a Natural Additive in Polyvinyl Alcohol/Chitosan Blend for Advanced Bioactive Food Packaging.” Journal of Polymer Science, ahead of print, July 4. https://doi.org/10.1002/pol.20240268.
Fu, Zhen-zhen, Sheng-jie Guo, Chen-xi Li, Ke Wang, Qin Zhang, and Qiang Fu. 2022. “Hydrogen-Bond-Dominated Mechanical Stretchability in PVA Films: From Phenomenological to Numerical Insights.” Physical Chemistry Chemical Physics 24 (3): 1885–95. https://doi.org/10.1039/D1CP03893A.
Jayarathna, Shishanthi, Mariette Andersson, and Roger Andersson. 2022. “Recent Advances in Starch-Based Blends and Composites for Bioplastics Applications.” Polymers 14 (21): 4557. https://doi.org/10.3390/polym14214557.
Kesuma, Ni Kadek Yuli, I Wayan Rai Widarta, and I Dewa Gede Mayun Permana. 2018. “Pengaruh Jenis Asam Dan Ph Pelarut Terhadap Karakteristik Pektin Dari Kulit Lemon (Citrus Limon).” Jurnal Ilmu Dan Teknologi Pangan (ITEPA) 7 (4): 192. https://doi.org/10.24843/itepa.2018.v07.i04.p06.
Khalid, Muhammad Yasir, Ramsha Imran, Zia Ullah Arif, et al. 2021. “Developments in Chemical Treatments, Manufacturing Techniques and Potential Applications of Natural-Fibers-Based Biodegradable Composites.” Coatings 11 (3): 293. https://doi.org/10.3390/coatings11030293.
Kumar, Santosh, and Sumit Bhowmik. 2023. “Extraction of Bio-Fillers from Natural Solid Wastes (Citrus Limetta Peel) and Characterization of the Physical, Mechanical, and Tribological Performance of Sustainable Biocomposites.” Journal of Material Cycles and Waste Management 25 (6): 3508–21. https://doi.org/10.1007/s10163-023-01773-x.
Lee, WooSeok, JaeHyeon Kim, and Tai Gyu Lee. 2025. “Certifications and Testing Methods for Biodegradable Plastics.” Reviews in Chemical Engineering 41 (2): 125–46. https://doi.org/10.1515/revce-2024-0061.
Liu, Baodong, Jianhua Zhang, and Hongge Guo. 2022. “Research Progress of Polyvinyl Alcohol Water-Resistant Film Materials.” Membranes 12 (3). https://doi.org/10.3390/membranes12030347.
Lubis, Pramdya A.T., Achmad Jusuf Zulfikar, and Iswandi Iswandi. 2022. “Analisis Kekuatan Tarik Belah Komposit Laminat Jute Sebagai Penguat Beton Kolom Silinder Berdasarkan Metode Penyerapan Energi Bahan.” IRA Jurnal Teknik Mesin Dan Aplikasinya (IRAJTMA) 1 (2): 55–64. https://doi.org/10.56862/irajtma.v1i2.21.
Mahardika, Melbi, Mochamad Asrofi, Devita Amelia, Edi Syafri, Sanjay Mavinkere Rangappa, and Suchart Siengchin. 2021. “Tensile Strength and Moisture Resistance Properties of Biocomposite Films Based on Polyvinyl Alcohol (PVA) with Cellulose as Reinforcement from Durian Peel Fibers.” E3S Web Conf. 302. https://doi.org/10.1051/e3sconf/202130202001.
Mahardika, Melbi, Nanang Masruchin, Devita Amelia, et al. 2024. “Nanocellulose Reinforced Polyvinyl Alcohol-Based Bio-Nanocomposite Films: Improved Mechanical, UV-Light Barrier, and Thermal Properties.” RSC Advances 14 (32): 23232–39. https://doi.org/10.1039/D4RA04205K.
Mittal, Aanchal, Sangeeta Garg, and Shailendra Bajpai. 2020. “Thermal Decomposition Kinetics and Properties of Grafted Barley Husk Reinforced PVA/Starch Composite Films for Packaging Applications.” Carbohydrate Polymers 240: 116225. https://doi.org/10.1016/j.carbpol.2020.116225.
Mohammed, Abdulrahman A B A, Zaimah Hasan, Abdoulhdi A Borhana Omran, et al. 2023. “Effect of Sugar Palm Fibers on the Properties of Blended Wheat Starch/Polyvinyl Alcohol (PVA) -Based Biocomposite Films.” Journal of Materials Research and Technology 24: 1043–55. https://doi.org/10.1016/j.jmrt.2023.02.027.
Maulana, M. R., Fauji S, A. ., Iswandi, I., & Umroh, B. . (2025). Design of a Polymer Composite Shredding Machine for Fuel Cell Component Applications. IRA Jurnal Teknik Mesin Dan Aplikasinya (IRAJTMA), 4(2), 238–244. https://doi.org/10.56862/irajtma.v4i2.285.
Pandit, Abhay, and Rakesh Kumar. 2021. “A Review on Production, Characterization and Application of Bacterial Cellulose and Its Biocomposites.” Journal of Polymers and the Environment 29 (9): 2738–55. https://doi.org/10.1007/s10924-021-02079-5.
Patil, Sharmila, Ashok Kumar Bharimalla, Archana Mahapatra, et al. 2021. “Effect of Polymer Blending on Mechanical and Barrier Properties of Starch-Polyvinyl Alcohol Based Biodegradable Composite Films.” Food Bioscience 44 (December): 101352. https://doi.org/10.1016/j.fbio.2021.101352.
Pradiza, Revvan Rifada, Dedi Dwilaksana, Melbi Mahardika, et al. 2025. “Morphology and Tensile Properties of Biocomposite Based Polyvinyl Alcohol and Cassava Starch Reinforced by Lemon Peel Fiber.” International Journal of Agriculture and Biosciences 14 (4): 549–55. https://doi.org/10.47278/journal.ijab/2025.051.
Pangaribuan, R. P. ., & Iswandi, I. (2025). Design of Composite Polymer Crusher Machine: Capacity 10 kg/Hour. IRA Jurnal Teknik Mesin Dan Aplikasinya (IRAJTMA), 4(2), 9–12. https://doi.org/10.56862/irajtma.v4i2.283.
Rahim Labbafzadeh, Minoush, and Mohammad Hassan Vakili. 2022. “Application of Magnetic Electrospun Polyvinyl Alcohol/Collagen Nanofibres for Drug Delivery Systems.” Molecular Simulation 48 (1): 1–7. https://doi.org/10.1080/08927022.2020.1783462.
Rahman Khan, Mohammad Mizanur, Md. Mahamudul Hasan Rumon, and Mobinul Islam. 2024. “Synthesis, Rheology, Morphology, and Mechanical Properties of Biodegradable PVA-Based Composite Films: A Review on Recent Progress.” Processes 12 (12): 2880. https://doi.org/10.3390/pr12122880.
Rangappa, Sanjay Mavinkere, Suchart Siengchin, and Hom Nath Dhakal. 2020. “Green-Composites: Ecofriendly and Sustainability.” Applied Science and Engineering Progress 13 (3). https://doi.org/10.14416/j.asep.2020.06.001.
Rifada Pradiza, Revvan, Mochamad Asrofi, Haris Setyawan, et al. 2025. “1 - Introduction of Natural Fiber and Its Surface Modification.” In Surface Modification and Coating of Fibers, Polymers, and Composites, edited by Rajeshkumar Lakshminarasimhan, Sathish Kumar Palaniappan, Ramesh Manickam, Sanjay Mavinkere Rangappa, and Suchart Siengchin. Elsevier. https://doi.org/10.1016/B978-0-443-22029-6.00001-0.
Satyanarayana, K.G., and V.S. Prasad. 2016. “Starch‐Based ‘Green’ Composites.” In Biodegradable Green Composites. Wiley. https://doi.org/10.1002/9781118911068.ch8.
Sabandi,A A. I., Mohamad Razlan, Z., Maruyama, N., Eswanto, E., Abu Bakar, S., Rani, M. F. H., … Wan Ahmad, W. K. (2025). Impact of Wet and Dry Ambient Conditions on the Lifespan of Lithium-Ion Polymer Batteries: A Correlation Analysis by Cycle Life Experiment. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences, 131(2), 26–39. https://doi.org/10.37934/arfmts.131.2.2639.
Tabassum, Noshabah, Uzaira Rafique, Maria Qayyum, Abdallah A. A. Mohammed, Saira Asif, and Awais Bokhari. 2024. “Kaolin–Polyvinyl Alcohol–Potato Starch Composite Films for Environmentally Friendly Packaging: Optimization and Characterization.” Journal of Composites Science 8 (1): 29. https://doi.org/10.3390/jcs8010029.
Wang, Mengxia, Xiaran Miao, Hui Li, and Chunhai Chen. 2022. “Effect of Length of Cellulose Nanofibers on Mechanical Reinforcement of Polyvinyl Alcohol.” Polymers 14 (1). https://doi.org/10.3390/polym14010128.
Wang, Yanli, Junwei He, Liming Zou, Yao Lu, and Yan Vivian Li. 2024. “High Performance Polyvinyl Alcohol/Lignin Fibers with Excellent Mechanical and Water Resistance Properties.” International Journal of Biological Macromolecules 266 (May): 131244. https://doi.org/10.1016/j.ijbiomac.2024.131244.
Yao, Xiao, Xue Yang, Yisang Lu, Yinyuan Qiu, and Qinda Zeng. 2024. “Review of the Synthesis and Degradation Mechanisms of Some Biodegradable Polymers in Natural Environments.” Polymers 17 (1): 66. https://doi.org/10.3390/polym17010066.
Zhang, Huan, Yuan Chen, Shanshan Wang, et al. 2020. “Extraction and Comparison of Cellulose Nanocrystals from Lemon (Citrus Limon) Seeds Using Sulfuric Acid Hydrolysis and Oxidation Methods.” Carbohydrate Polymers 238: 116180. https://doi.org/10.1016/j.carbpol.2020.116180.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2026 IRA Jurnal Teknik Mesin dan Aplikasinya (IRAJTMA)

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.














